Visible light promoted hydration of alkynes catalyzed by rhodium(III) porphyrins.
نویسندگان
چکیده
Visible light promoted hydration of a wide scope of alkynes to ketones catalyzed by rhodium(III) porphyrin complexes was described. The key intermediate β-carbonyl alkyl was observed and independently synthesized. The rate of photolysis is over two orders of magnitude faster than that of the thermal process.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 51 59 شماره
صفحات -
تاریخ انتشار 2015